However, I've had a bit of experience upgrading from Standard Edition (SE) to Enterprise Edition (EE) and it's really easier than these documents make it seem. Assuming that you're installing EE on the same server as SE, I would detach the current user databases using sp_detach_db procedure. Take down SE, install and bring up EE. Then, reattach the user databases using sp_attach_dp procedure. You should be good to go!
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